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Register a new userWarming the early Earth - CO2 reconsidered
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P. von Paris
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Despite a fainter Sun, the surface of the early Earth was mostly ice-free. Proposed solutions to this so-called faint young Sun problem have usually involved higher amounts of greenhouse gases than present in the modern-day atmosphere. However, geological evidence seemed to indicate that the atmospheric CO2 concentrations during the Archaean and Proterozoic were far too low to keep the surface from freezing. With a radiative-convective model including new, updated thermal absorption coefficients, we found that the amount of CO2 necessary to obtain 273 K at the surface is reduced up to an order of magnitude compared to previous studies. For the late Archaean and early Proterozoic period of the Earth, we calculate that CO2 partial pressures of only about 2.9 mb are required to keep its surface from freezing which is compatible with the amount inferred from sediment studies. This conclusion was not significantly changed when we varied model parameters such as relative humidity or surface albedo, obtaining CO2 partial pressures for the late Archaean between 1.5 and 5.5 mb. Thus, the contradiction between sediment data and model results disappears for the late Archaean and early Proterozoic.
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The presence of valleys on ancient terrains of Mars suggest that liquid water flowed on the martian surface 3.8 billion years ago or before. The above-freezing temperatures required to explain valley formation could have been transient, in response to frequent large meteorite impacts on early Mars, or they could have been caused by long-lived greenhouse warming. Climate models that consider only the greenhouse gases carbon dioxide and water vapor have been unable to recreate warm surface conditions, given the lower solar luminosity at that time. Here we use a one-dimensional climate model to demonstrate that an atmosphere containing 1.3-4 bar of CO2 and water vapor, along with 5 to 20 percent H2, could have raised the mean surface temperature of early Mars above the freezing point of water. Vigorous volcanic outgassing from a highly reduced early martian mantle is expected to provide sufficient atmospheric H2 and CO2, the latter from the photochemical oxidation of outgassed CH4 and CO, to form a CO2-H2 greenhouse. Such a dense early martian atmosphere is consistent with independent estimates of surface pressure based on cratering data.
Explaining the evidence for surface liquid water on early Mars has been a challenge for climate modelers, as the sun was ~30% less luminous during the late-Noachian. We propose that the additional greenhouse forcing of CO2-H2 collision-induced absorption is capable of bringing the surface temperature above freezing and can put early Mars into a limit-cycling regime. Limit cycles occur when insolation is low and CO2 outgassing rates are unable to balance with the rapid drawdown of CO2 during warm weathering periods. Planets in this regime will alternate between global glaciation and transient warm climate phases. This mechanism is capable of explaining the geomorphological evidence for transient warm periods in the martian record. Previous work has shown that collision-induced absorption of CO2-H2 was capable of deglaciating early Mars, but only with high H2 outgassing rates (greater than ~600 Tmol/yr) and at high surface pressures (between 3 to 4 bars). We used new theoretically derived collision-induced absorption coefficients for CO2-H2 to reevaluate the climate limit cycling hypothesis for early Mars. Using the new and stronger absorption coefficients in our 1-dimensional radiative convective model as well as our energy balance model, we find that limit cycling can occur with an H2 outgassing rate as low as ~300 Tmol/yr at surface pressures below 3 bars. Our results agree more closely with paleoparameters for early martian surface pressure and hydrogen abundance.
The emergence of life on the Earth has required a prior organic chemistry leading to the formation of prebiotic molecules. The origin and the evolution of the organic matter on the early Earth is not yet firmly understood. Several hypothesis, possibly complementary, are considered. They can be divided in two categories: endogenous and exogenous sources. In this work we investigate the contribution of a specific endogenous source: the organic chemistry occurring in the ionosphere of the early Earth where the significant VUV contribution of the young Sun involved an efficient formation of reactive species. We address the issue whether this chemistry can lead to the formation of complex organic compounds with CO2 as only source of carbon in an early atmosphere made of N2, CO2 and H2, by mimicking experimentally this type of chemistry using a low pressure plasma reactor. By analyzing the gaseous phase composition, we strictly identified the formation of H2O, NH3, N2O and C2N2. The formation of a solid organic phase is also observed, confirming the possibility to trigger organic chemistry in the upper atmosphere of the early Earth. The identification of Nitrogen-bearing chemical functions in the solid highlights the possibility for an efficient ionospheric chemistry to provide prebiotic material on the early Earth.
The hypothesis of a companion object (Nemesis) orbiting the Sun was motivated by the claim of a terrestrial extinction periodicity, thought to be mediated by comet showers. The orbit of a distant companion to the Sun is expected to be perturbed by the Galactic tidal field and encounters with passing stars, which will induce variation in the period. We examine the evidence for the previously proposed periodicity, using two modern, greatly improved paleontological datasets of fossil biodiversity. We find that there is a narrow peak at 27 My in the cross-spectrum of extinction intensity time series between these independent datasets. This periodicity extends over a time period nearly twice that for which it was originally noted. An excess of extinction events are associated with this periodicity at 99% confidence. In this sense we confirm the originally noted feature in the time series for extinction. However, we find that it displays extremely regular timing for about 0.5 Gy. The regularity of the timing compared with earlier calculations of orbital perturbation would seem to exclude the Nemesis hypothesis as a causal factor.
The quasiparticle random phase approximation is used to study the properties of the wobbling bands in $^{163}$Lu. Assuming that the wobbling mode represents pure isoscalar orientation oscillations results in too low wobbling frequencies and too strong M1 transitions between the one- and zero-phonon wobbling bands. The inclusion of an LL interaction, which couples the wobbling mode to the scissors mode, generates the right upshift of the wobbling frequencies and the right suppression of the B(M1)$_{out}$ values toward the experimental values. In analogy to the quenching of low-energy E1 transition by coupling to the Isovector Giant Dipole Resonance, a general reduction of the M1 transitions between quasiparticle configurations caused by coupling to the scissors mode is suggested.
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