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Register a new userLarge excess of heavy nitrogen in both hydrogen cyanide and cyanogen from comet 17P/Holmes
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From millimeter and optical observations of the Jupiter-family comet 17P/Holmes performed soon after its huge outburst of October 24, 2007, we derive 14 N/15N = 139 +/- 26 in HCN, and 14N/15N = 165 +/- 40 in CN, establishing that HCN has the same non-terrestrial isotopic composition as CN. The same conclusion is obtained for the long-period comet C/1995 O1 (Hale-Bopp) after a reanalysis of previously published measurements. These results are compatible with HCN being the prime parent of CN in cometary atmospheres. The 15N excess relative to the Earth atmospheric value indicates that N-bearing volatiles in the solar nebula underwent important N isotopic fractionation at some stage of Solar System formation. HCN molecules never isotopically equilibrated with the main nitrogen reservoir in the solar nebula before being incorporated in Oort-cloud and Kuiper-belt comets. The 12C/13C ratios in HCN and CN are measured to be consistent with the terrestrial value.
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Based on millimeter-wavelength continuum observations we suggest that the recent spectacle of comet 17P/Holmes can be explained by a thick, air-tight dust cover and the effects of H2O sublimation, which started when the comet arrived at the heliocentric distance <= 2.5 AU. The porous structure inside the nucleus provided enough surface for additional sublimation, which eventually led to the break up of the dust cover and to the observed outburst. The magnitude of the particle burst can be explained by the energy provided by insolation, stored in the dust cover and the nucleus within the months before the outburst: the subliming surface within the nucleus is more than one order of magnitude larger than the geometric surface of the nucleus -- possibly an indication of the latters porous structure. Another surprise is that the abundance ratios of several molecular species with respect to H2O are variable. During this apparition, comet Holmes lost about 3% of its mass, corresponding to a dirty ice layer of 20m.
We present high angular resolution Submillimeter Array observations ofthe outbursting Jupiter family comet 17P/Holmes on 2007 October 26-29, achieving a spatial resolution of 2.5, or ~3000 km at the comet distance. The observations resulted in detections of the rotational lines CO 3-2, HCN 4-3, H$^{13}$CN 4-3, CS 7-6, H$_2$CO 3$_{1,2}$-2$_{1,1}$, H$_2$S 2$_{2,0}$-2$_{1,1}$, and multiple CH$_3$OH lines, along with the associated dust continuum at 221 and 349 GHz. The continuum has a spectral index of 2.7$pm$0.3, slightly steeper than blackbody emission from large dust particles. From the imaging data, we identify two components in the molecular emission. One component is characterized by a relatively broad line width (~1 km s$^{-1}$ FWHM) exhibiting a symmetric outgassing pattern with respect to the nucleus position. The second component has a narrower line width (<0.5 km s$^{-1}$ FWHM) with the line center red-shifted by 0.1-0.2 km s$^{-1}$ (cometocentric frame), and shows a velocity shift across the nucleus position with the position angle gradually changing from 66 to 30 degrees within the four days of observations. We determine distinctly different CO/HCN ratios for each of the components. For the broad-line component we find CO/HCN <7, while in the narrow-line component, CO/HCN = 40$pm$5. We hypothesize that the narrow-line component originates from the ice grain halo found in near-nucleus photometry, believed to be created by sublimating recently released ice grains around the nucleus during the outburst. In this interpretation, the high CO/HCN ratio of this component reflects the more pristine volatile composition of nucleus material released in the outburst.
We performed a monitoring observation of a Jupiter-Family comet, 17P/Holmes, during its 2014 perihelion passage to investigate its secular change in activity. The comet has drawn the attention of astronomers since its historic outburst in 2007, and this occasion was its first perihelion passage since then. We analyzed the obtained data using aperture photometry package and derived the Afrho parameter, a proxy for the dust production rate. We found that Afrho showed asymmetric properties with respect to the perihelion passage: it increased moderately from 100 cm at the heliocentric distance r_h=2.6-3.1 AU to a maximal value of 185 cm at r_h = 2.2 AU (near the perihelion) during the inbound orbit, while dropping rapidly to 35 cm at r_h = 3.2 AU during the outbound orbit. We applied a model for characterizing dust production rates as a function of r_h and found that the fractional active area of the cometary nucleus had dropped from 20%-40% in 2008-2011 (around the aphelion) to 0.1%-0.3% in 2014-2015 (around the perihelion). This result suggests that a dust mantle would have developed rapidly in only one orbital revolution around the sun. Although a minor eruption was observed on UT 2015 January 26 at r_h = 3.0 AU, the areas excavated by the 2007 outburst would be covered with a layer of dust (<~ 10 cm depth) which would be enough to insulate the subsurface ice and to keep the nucleus in a state of low activity.
Hydrogen cyanide (HCN) is a key feedstock molecule for the production of lifes building blocks. The formation of HCN in an N$_2$-rich atmospheres requires first that the triple bond between N$equiv$N be severed, and then that the atomic nitrogen find a carbon atom. These two tasks can be accomplished via photochemistry, lightning, impacts, or volcanism. The key requirements for producing appreciable amounts of HCN are the free availability of N$_2$ and a local carbon to oxygen ratio of C/O $geq 1$. We discuss the chemical mechanisms by which HCN can be formed and destroyed on rocky exoplanets with Earth-like N$_2$ content and surface water inventories, varying the oxidation state of the dominant carbon-containing atmospheric species. HCN is most readily produced in an atmosphere rich in methane (CH$_4$) or acetylene (C$_2$H$_2$), but can also be produced in significant amounts ($> 1$ ppm) within CO-dominated atmospheres. Methane is not necessary for the production of HCN. We show how destruction of HCN in a CO$_2$-rich atmosphere depends critically on the poorly-constrained energetic barrier for the reaction of HCN with atomic oxygen. We discuss the implications of our results for detecting photochemically produced HCN, for concentrating HCN on the planets surface, and its importance for prebiotic chemistry.
We present results for Chandra observations of comets, 17P/Holmes (17P) and 8P/Tuttle (8P). 17P was observed for 30 ksec right after its major outburst, on 31 Oct 2007 (10:07 UT) and comet 8P/Tuttle was observed in 2008 January for 47 ksec. During the two Chandra observations, 17P was producing at least 100 times more water than 8P but was 2.2 times further away from the Sun. Also, 17P is the first comet observed at high latitude (+19.1 degrees) during solar minimum, while 8P was observed at a lower solar latitude (3.4 degrees). The X-ray spectrum of 17P is unusually soft with little significant emission at energies above 500 eV. Depending on our choice of background, we derive a 300 to 1000 eV flux of 0.5 to 4.5 x 10^-13 ergs/cm2/sec, with over 90% of the emission in the 300 to 400 eV range. This corresponds to an X-ray luminosity between 0.4 to 3.3 x 10^15 ergs/sec. 17Ps lack of X-rays in the 400 to 1000 eV range, in a simple picture, may be attributed to the polar solar wind, which is depleted in highly charged ions. 8P/Tuttle was much brighter, with an average count rate of 0.20 counts/s in the 300 to 1000 eV range. We derive an average X-ray flux in this range of 9.4 x 10^-13 ergs/cm2/sec and an X-ray luminosity for the comet of 1.7 x 10^14 ergs/sec. The light curve showed a dramatic decrease in flux of over 60% between observations on January 1st and 4th. When comparing outer regions of the coma to inner regions, its spectra showed a decrease in ratios of CVI/CV, OVIII/OVII, as predicted by recent solar wind charge exchange emission models. There are remarkable differences between the X-ray emission from these two comets, further demonstrating the qualities of cometary X-ray observations, and solar wind charge exchange emission in more general as a means of remote diagnostics of the interaction of astrophysical plasmas.
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