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Register a new userMechanism of Collisional Spin Relaxation in Triplet-Sigma Molecules
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We measure and theoretically determine the effect of molecular rotational splitting on Zeeman relaxation rates in collisions of cold Triplet-Sigma molecules with helium atoms in a magnetic field. All four stable isotopomers of the imidogen (NH) molecule are magnetically trapped and studied in collisions with 3He and 4He. The 4He data support the predicted inverse square dependence of the collision induced Zeeman relaxation rate coefficient on the molecular rotational constant B. The measured 3He rate coefficients are much larger than 4He and depend less strongly on B, and the theoretical analysis indicates they are strongly affected by a shape resonance. The results demonstrate the influence of molecular structure on collisional energy transfer at low temperatures.
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Imidogen (NH) radicals are magnetically trapped and their Zeeman relaxation and energy transport collision cross sections with helium are measured. Continuous buffer-gas loading of the trap is direct from a room-temperature molecular beam. The Zeeman relaxation (inelastic) cross section of magnetically trapped electronic, vibrational and rotational ground state imidogen in collisions with He-3 is measured to be 3.8 +/- 1.1 E-19 cm^2 at 710 mK. The NH-He energy transport cross section is also measured, indicating a ratio of diffusive to inelastic cross sections of gamma = 7 E4 in agreement with the recent theory of Krems et al. (PRA 68 051401(R) (2003))
We present calculations of spin-relaxation rates of alkali-metal atoms due to the spin-axis interaction acting in binary collisions between the atoms. We show that for the high-temperature conditions of interest here, the spin relaxation rates calculated with classical-path trajectories are nearly the same as those calculated with the distorted-wave Born approximation. We compare these calculations to recent experiments that used magnetic decoupling to isolate spin relaxation due to binary collisions from that due to the formation of triplet van-der-Waals molecules. The values of the spin-axis coupling coefficients deduced from measurements of binary collision rates are consistent with those deduced from molecular decoupling experiments. All the experimental data is consistent with a simple and physically plausible scaling law for the spin-axis coupling coefficients.
We observe magnetic trapping of atomic nitrogen (14^N) and cotrapping of ground state imidogen (14^NH, X-triplet-Sigma-). Both are loaded directly from a room temperature beam via buffer gas cooling. We trap approximately 1 * 10^11 14^N atoms at a peak density of 5 * 10^11 cm^-3 at 550 mK. The 12 +5/-3 s 1/e lifetime of atomic nitrogen in the trap is limited by elastic collisions with the helium buffer gas. Cotrapping of 14^N and 14^NH is accomplished, with 10^8 NH trapped molecules at a peak density of 10^8 cm^-3. We observe no spin relaxation of nitrogen in collisions with helium.
We present a theoretical study of the Zeeman relaxation of the magnetically trappable lowest field seeking state of MnH(^7 Sigma) in collisions with 3He. We analyze the collisional Zeeman transition mechanism as a function of the final diatomic state and its variation as a function of an applied magnetic field. We show that as a result of this mechanism the levels with Delta Mj>2 give negligible contributions to the Zeemam relaxation cross section. We also compare our results to the experimental cross sections obtained from the buffer gas cooling and magnetic trapping of this molecule and investigate the dependence of the Zeeman relaxation cross section on the accuracy of the three body interaction at ultralow energies.
We predict the resonance enhanced magnetic field dependence of atom-dimer relaxation and three-body recombination rates in a $^{87}$Rb Bose-Einstein condensate (BEC) close to 1007 G. Our exact treatments of three-particle scattering explicitly include the dependence of the interactions on the atomic Zeeman levels. The Feshbach resonance distorts the entire diatomic energy spectrum causing interferences in both loss phenomena. Our two independent experiments confirm the predicted recombination loss over a range of rate constants that spans four orders of magnitude.
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