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Register a new userNonlinear NMR dynamics in hyperpolarized liquid 3He
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Emmanuel Baudin
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In a highly polarized liquid (laser-polarized 3He-4He mixtures in our experiment), dipolar magnetic interactions within the liquid introduce a significant nonlinear and nonlocal contribution to the Bloch equation that leads to instabilities during NMR evolution. We have launched a study of these instabilities using spin echo techniques. At high magnetizations, a simple 180 degree rf pulse fails to refocus magnetization, so we use a standard solid-state NMR pulse sequence: the magic sandwich. We report an experimental and numerical investigation of the effect of this sequence on unstable NMR evolution. Using a series of repeated magic sandwich sequences, the transverse magnetization lifetime can be increased by up to three orders of magnitude.
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Long-range magnetic interactions in highly magnetised liquids (laser-polarised 3He-4He dilute mixtures at 1 K in our experiment) introduce a significant non-linear and non-local contribution to the evolution of nuclear magnetisation that leads to instabilities during free precession. We recently demonstrated that a multi-echo NMR sequence, based on the magic sandwich pulse scheme developed for solid-state NMR, can be used to stabilise the magnetisation against the effect of distant dipolar fields. Here, we report investigations of echo attenuation in an applied field gradient that show the potential of this NMR sequence for spin diffusion measurements at high magnetisation densities.
We report on orientation of the order parameter in the 3He-A and 3He-B phases caused by aerogel anisotropy. In 3He-A we have observed relatively homogeneous NMR line with an anomalously large negative frequency shift. We can attribute this effect to an orientation of orbital momentum along the axis of density anisotropy. The similar orientation effect we have seen in 3He-B. We can measure the A-phase Leggett frequency, which shows the same energy gap suppression as in the B-phase. We observe a correlation of A - B transition temperature and NMR frequency shift.
The dynamics of 3He atoms in solid 4He have been investigated by measuring the NMR relaxation times T1, T2 in the region where a significant non-classical rotational inertia fraction (NCRIF) has been reported. For 3He concentrations x3 = 16 ppm and 24 ppm, changes are observed for both the spin-lattice relaxation time T1 and the spin-spin relaxation time T2 at the temperatures corresponding to the onset of NCRIF and, at lower temperatures, to the 3He-4He phase separation. The magnitudes of T1 and T2 at temperatures above the phase separation agree roughly with existing theory based on the tunneling of 3He impurities in the elastic strain field due to isotopic mismatch. However, a distinct peak in T1 and a less well-resolved feature in T2 are observed near the reported NCRIF onset temperature, in contrast to the temperature-independent relaxation times predicted by the tunneling theory.
Two nanosized PrF3 samples were synthesized using two different procedures. The X-ray and HRTEM experiments showed high crystallinity of synthesized sample. Comparison of enhanced 141Pr NMR spectra of microsized (45 $mu$m) and nanosized PrF3 powder is presented. Experimental data on spin kinetics of 3He in contact with PrF3 nanoparticles at T = 1.5 K are reported.
It was found that two different spin states of the A-like phase can be obtained in aerogel sample. In one of these states we have observed the signal of the longitudinal NMR, while in another state no trace of such a signal was found. The states also have different properties in transverse NMR experiments. Longitudinal NMR signal was also observed in the B-like phase of 3He in aerogel.
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