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When a solid plate is withdrawn from a liquid bath, a receding contact line is formed where solid, liquid, and gas meet. Above a critical speed $U_{cr}$, a stationary contact line can no longer exist and the solid will eventually be covered completely by a liquid film. Here we show that the bifurcation diagram of this coating transition changes qualitatively, from discontinuous to continuous, when decreasing the inclination angle of the plate. We show that this effect is governed by the presence of capillary waves, illustrating that the large scale flow strongly effects the maximum speed of dewetting.
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The dynamics of wetting and dewetting is largely determined by the velocity field near the contact lines. For water drops it has been observed that adding surfactant decreases the dynamic receding contact angle even at a concentration much lower than the critical micelle concentration (CMC). To better understand why surfactants have such a drastic effect on drop dynamics, we constructed a dedicated a setup on an inverted microscope, in which an aqueous drop is held stationary while the transparent substrate is moved horizontally. Using astigmatism particle tracking velocimetry, we track the 3D displacement of the tracer particles in the flow. We study how surfactants alter the flow dynamics near the receding contact line of a moving drop for capillary numbers in the order of $10^{-6}$. Even for surfactant concentrations $c$ far below the critical micelle concentration ($c ll$ CMC) Marangoni stresses change the flow drastically. We discuss our results first in a 2D model that considers advective and diffusive surfactant transport and deduce estimates of the magnitude and scaling of the Marangoni stress from this. Modeling and experiment agree that a tiny gradient in surface tension of a few $mu N , m^{-1}$ is enough to alter the flow profile significantly. The variation of the Marangoni stress with the distance from the contact line suggests that the 2D advection-diffusion model has to be extended to a full 3D model. The effect is ubiquitous, since surfactant is present in many technical and natural dewetting processes either deliberately or as contamination.
We investigate the internal flow pattern of an evaporating droplet using tomographic particle image velocimetry (PIV) when the contact line non-uniformly recedes. We observe a three-dimensional azimuthal vortex pair while the contact line non-uniformly recedes and the symmetry-breaking flow field is maintained during the evaporation. Based on the experimental results, we show that the vorticity magnitude of the internal flow is related to the relative contact line motion. Furthermore, to explain how the azimuthal vortex pair flow is created, we develop a theoretical model by taking into account the relation between the contact line motion and evaporating flux. Finally, we show that the theoretical model has a good agreement with experimental results.
We discuss an evaporation-induced wetting transition on superhydrophobic stripes, and show that depending on the elastic energy of the deformed contact line, which determines the value of an instantaneous effective contact angle, two different scenarios occur. For relatively dilute stripes the receding angle is above 90$^circ$, and the sudden impalement transition happens due to an increase of a curvature of an evaporating drop. For dense stripes the slow impregnation transition commences when the effective angle reaches 90$^circ$ and represents the impregnation of the grooves from the triple contact line towards the drop center.
The entrainment of air by advancing contact lines is studied by plunging a solid plate into a very viscous liquid. Above a threshold velocity, we observe the formation of an extended air film, typically 10 microns thick, which subsequently decays into air bubbles. Exploring a large range of viscous liquids, we find an unexpectedly weak dependence of entrainment speed on liquid viscosity, pointing towards a crucial role of the flow inside the air film. This induces a striking asymmetry between wetting and dewetting: while the breakup of the air film strongly resembles the dewetting of a liquid film, the wetting speeds are larger by orders of magnitude.
We study the dynamics of the interface between two immiscible fluids in contact with a chemically homogeneous moving solid plate. We consider the generic case of two fluids with any viscosity ratio and of a plate moving in either directions (pulled or pushed in the bath). The problem is studied by a combination of two models, namely an extension to finite viscosity ratio of the lubrication theory and a Lattice Boltzmann method. Both methods allow to resolve, in different ways, the viscous singularity at the triple contact between the two fluids and the wall. We find a good agreement between the two models particularly for small capillary numbers. When the solid plate moves fast enough, the entrainment of one fluid into the other one can occur. The extension of the lubrication model to the case of a non-zero air viscosity, as developed here, allows us to study the dependence of the critical capillary number for air entrainment on the other parameters in the problem (contact angle and viscosity ratio).
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