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Accurate long-range coefficients for two excited like isotope He atoms: He($2 ^1P$)--He($2 ^1P$), He($2 ^1P$)--He($2 ^3P$), and He($2 ^3P$)--He($2 ^3P$)

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 Added by Jun-Yi Zhang
 Publication date 2007
  fields Physics
and research's language is English




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A general formalism is used to express the long-range potential energies in inverse powers of the separation distance between two like atomic or molecular systems with $P$ symmetries. The long-range molecular interaction coefficients are calculated for the molecular symmetries $Delta$, $Pi$, and $Sigma$, arising from the following interactions: He($2 ^1P$)--He($2 ^1P$), He($2 ^1P$)--He($2 ^3P$), and He($2 ^3P$)--He($2 ^3P$). The electric quadrupole-quadrupole term, $C_{5}$, the van der Waals (dispersion) term $C_{6}$, and higher-order terms, $C_{8}$, and $C_{10}$, are calculated textit{ab initio} using accurate variational wave functions in Hylleraas coordinates with finite nuclear mass effects. A comparison is made with previously published results where available.



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Four light-mass nuclei are considered by an effective two-body clusterisation method; $^6$Li as $^2$H$+^4$He, $^7$Li as $^3$H$+^4$He, $^7$Be as $^3$He$+^4$He, and $^8$Be as $^4$He$+^4$He. The low-energy spectrum of each is determined from single-channel Lippmann-Schwinger equations, as are low-energy elastic scattering cross sections for the $^2$H$+^4$He system. These are presented at many angles and energies for which there are data. While some of these systems may be more fully described by many-body theories, this work establishes that a large amount of data may be explained by these two-body clusterisations.
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We explore coherent control of Penning and associative ionization in cold collisions of metastable He$^*({2}^3text{S})$ atoms via the quantum interference between different states of the He$_2^*$ collision complex. By tuning the preparation coefficients of the initial atomic spin states, we can benefit from the quantum interference between molecular channels to maximize or minimize the cross sections for Penning and associative ionization. In particular, we find that we can enhance the ionization ratio by 30% in the cold regime. This work is significant for the coherent control of chemical reactions in the cold and ultracold regime.
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