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Register a new userInterplay between magnetic properties and thermoelectricity in misfit and Na cobaltates
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We present a comparative study of CoO2 layers in the Bi-misfit and NaxCoO2 cobaltates. Co NMR measures the intrinsic susceptibility of the Co layers and is not affected by spurious contributions. At low dopings where room-temperature thermopower (TEP) is large, Curie-Weiss susceptibilities are observed in both materials. But NMR and muSR experiments find neither charge nor spin order down to low temperatures in Bi-misfit, in contrast to the case of NaxCoO2. This demonstrates that metallicity, charge and magnetic orders are specific of the Na layers in NaxCoO2 whereas strong correlations are generic of the cobaltates physics and could explain the large TEP.
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We have performed Raman scattering investigations on the high energy magnetic excitations in a BiFeO$_3$ single crystal as a function of both temperature and laser excitation energy. A strong feature observed at 1250 cm$^{-1}$ in the Raman spectra has been previously assigned to two phonon overtone. We show here that its unusual frequency shift with the excitation energy and its asymmetric temperature dependent Fano lineshape reveal a strong coupling to magnetic excitations. In the same energy range, we have also identified the two-magnon excitation with a temperature dependence very similar to $alpha$-Fe$_2$O$_3$ hematite.
We present anisotropic transport and optical spectroscopy studies on EuCd_2As_2. The measurements reveal that EuCd_2As_2 is a low carrier density semimetal with moderate anisotropic resistivity ratio. The charge carriers experience very strong scattering from Eu magnetic moments, resulting in a Kondo-like increase of resistivity at low temperature. Below the antiferromagnetic transition temperature at $T_N$= 9.5 K, the resistivity drops sharply due to the reduced scattering from the ordered Eu moments. Nevertheless, the anisotropic ratio of $rho_c/rho_{ab}$ keeps increasing, suggesting that the antiferromagnetic coupling is along the c-axis. The optical spectroscopy measurement further reveals, besides an overdamped reflectance plasma edge at low energy, a strong coupling between phonon and electronic continuum. Our study suggests that EuCd_2As_2 is a promising candidate displaying intriguing interplay among charge, magnetism and the underlying crystal lattice.
Magnetic properties of polycrystalline CaMn1-xRuxO3 (x = 0 - 0.5) samples were investigated in the temperature range 4.2 - 250 K, under external magnetic field up to 15 kOe and under hydrostatic pressure up to 12 kbar. Transport properties of the samples with x = 0.1, 0.2, 0.4, 0.5 were also investigated under pressure up to 10 kbar. For x up to 0.4, the pressure was found to suppress ferromagnetic correlations and to increase the resistivity, while for x = 0.5 to act in the opposite way. While long ferromagnetic order is completely suppressed, in small clusters ferromagnetic correlations probably survive under pressure, as was revealed for CaMn0.9Ru0.1O3. The pressure effect on the magnetic interactions and on the volume of ferromagnetic phase was found to depend strongly on the Ru-content, and absolute value of the pressure coefficient of spontaneous magnetization was found to decrease practically linearly with increasing x in the range 0.1 < x < 0.5. The experimental data are discussed in the frame of proposed energy-level diagram, which includes magneto-impurity states at low and moderate Ru-doping and mixed-valence states of Ru presented by a strongly-correlated t2g-like band at heavy Ru-doping. An impact of disorder introduced by Ru-doping on the energy diagram and on derived magnetic interactions is discussed. Predictions of the model regarding the pressure effects on conductivity and temperature scales characteristic for magnetic interactions are in reasonable agreement with experiment.
Strong interplay of spin and charge/orbital degrees of freedom is the fundamental characteristic of the iron-based superconductors (FeSCs), which leads to the emergence of a nematic state as a rule in the vicinity of the antiferromagnetic state. Despite intense debate for many years, however, whether nematicity is driven by spin or orbital fluctuations remains unsettled. Here, by use of transport, magnetization, and $^{75}$As nuclear magnetic resonance (NMR) measurements, we show a striking transformation of the relationship between nematicity and spin fluctuations (SFs) in Na$_{1-x}$Li$_x$FeAs; For $xleq 0.02$, the nematic transition promotes SFs. In contrast, for $xgeq 0.03$, the system undergoes a non-magnetic phase transition at a temperature $T_0$ into a distinct nematic state that suppresses SFs. Such a drastic change of the spin fluctuation spectrum associated with nematicity by small doping is highly unusual, and provides insights into the origin and nature of nematicity in FeSCs.
The search for semiconductors with high thermoelectric figure of merit has been greatly aided by theoretical modeling of electron and phonon transport, both in bulk materials and in nanocomposites. Recent experiments have studied thermoelectric transport in ``strongly correlated materials derived by doping Mott insulators, whose insulating behavior without doping results from electron-electron repulsion, rather than from band structure as in semiconductors. Here a unified theory of electrical and thermal transport in the atomic and ``Heikes limit is applied to understand recent transport experiments on sodium cobaltate and other doped Mott insulators at room temperature and above. For optimal electron filling, a broad class of narrow-bandwidth correlated materials are shown to have power factors (the electronic portion of the thermoelectric figure of merit) as high at and above room temperature as in the best semiconductors.
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