Antimony sulfide (Sb2S3) and selenide (Sb2Se3) have emerged as promising earth-abundant alternatives among thin-film photovoltaic compounds. A distinguishing feature of these materials is their anisotropic crystal structures, which are composed of quasi-one-dimensional (1D) [Sb4X6]n ribbons. The interaction between ribbons has been reported to be van der Waals (vdW) in nature and Sb2X3 are thus commonly classified in the literature as 1D semiconductors. However, based on first-principles calculations, here we show that inter-ribbon interactions are present in Sb2X3 beyond the vdW regime. The origin of the anisotropic structures is related to the stereochemical activity of the Sb 5s lone pair according to electronic structure analysis. The impacts of structural anisotropy on the electronic and optical properties are further examined, including the presence of higher dimensional Fermi surfaces for charge carrier transport. Our study provides guidelines for optimising the performance of Sb2X3-based solar cells via device structuring based on the underlying crystal anisotropy.
Quantum spin Hall (QSH) insulator materials feature topologically protected edge states that can drastically reduce dissipation and are useful for the next-generation electronics. However, the nonvolatile control of topological edge state is still a challenge. In this paper, based on first-principles calculations, the switchable topological states are found in the van der Waals (vdW) heterostructures consisting of two dimensional (2D) Bi(111) bilayer (BL) and {alpha}-In2Se3 by reversing the electric polarization of the ferroelectric {alpha}-In2Se3. The topological switching results from the different charge transfer associated with the two opposite polarization states of {alpha}-In2Se3. This new topological switching mechanism has the unique advantages of being fully electrical as well as nonvolatile. Our finding provides an unprecedented approach to realize ferroelectric control of topological states in 2D materials, which will have great potential for applications in topological nanoscale electronics.
Agile satellites with advanced attitude maneuvering capability are the new generation of Earth observation satellites (EOSs). The continuous improvement in satellite technology and decrease in launch cost have boosted the development of agile EOSs (AEOSs). To efficiently employ the increasing orbiting AEOSs, the AEOS scheduling problem (AEOSSP) aiming to maximize the entire observation profit while satisfying all complex operational constraints, has received much attention over the past 20 years. The objectives of this paper are thus to summarize current research on AEOSSP, identify main accomplishments and highlight potential future research directions. To this end, general definitions of AEOSSP with operational constraints are described initially, followed by its three typical variations including different definitions of observation profit, multi-objective function and autonomous model. A detailed literature review from 1997 up to 2019 is then presented in line with four different solution methods, i.e., exact method, heuristic, metaheuristic and machine learning. Finally, we discuss a number of topics worth pursuing in the future.
The Earth observation satellites (EOSs) are specially designed to collect images according to user requirements. The agile EOSs (AEOS), with stronger attitude maneuverability, greatly improve the observation capability, while increasing the complexity in scheduling. We address a multiple AEOSs scheduling with multiple observations for the first time}, where the objective function aims to maximize the entire observation profit over a fixed horizon. The profit attained by multiple observations for each target is nonlinear to the number of observations. We model the multiple AEOSs scheduling as a specific interval scheduling problem with each satellite orbit respected as machine. Then A column generation based framework is developed to solve this problem, in which we deal with the pricing problems with a label-setting algorithm. Extensive simulations are conducted on the basis of a Chinas AEOS constellation, and the results indicate the optimality gap is less than 3% on average, which validates the performance of the scheduling solution obtained by the proposed framework. We also compare the framework in the conventional EOS scheduling.
The Earth observation satellites (EOSs) scheduling is of great importance to achieve efficient observation missions. The agile EOSs (AEOS) with stronger attitude maneuvering capacity can greatly improve observation efficiency while increasing scheduling complexity. The multiple AEOSs, oversubscribed targets scheduling problem with multiple observations are addressed, and the potential observation missions are modeled as nodes in the complex networks. To solve the problem, an improved feedback structured heuristic is designed by defining the node and target importance factors. On the basis of a real world Chinese AEOS constellation, simulation experiments are conducted to validate the heuristic efficiency in comparison with a constructive algorithm and a structured genetic algorithm.
