The Coulomb repulsion, impeding electrons motion, has an important impact on the charge dynamics. It mainly causes a reduction of the effective metallic Drude weight (proportional to the so-called optical kinetic energy), encountered in the optical conductivity, with respect to the expectation within the nearly-free electron limit (defining the so-called band kinetic energy), as evinced from band-structure theory. In principle, the ratio between the optical and band kinetic energy allows defining the degree of electronic correlations. Through spectral weight arguments based on the excitation spectrum, we provide an experimental tool, free from any theoretical or band-structure based assumptions, in order to estimate the degree of electronic correlations in several systems. We first address the novel iron-pnictide superconductors, which serve to set the stage for our approach. We then revisit a large variety of materials, ranging from superconductors, to Kondo-like systems as well as materials close to the Mott-insulating state. As comparison we also tackle materials, where the electron-phonon coupling dominates. We establish a direct relationship between the strength of interaction and the resulting reduction of the optical kinetic energy of the itinerant charge carriers.
We investigate the rare-earth polychalcogenide $R_2$Te$_5$ ($R$=Nd, Sm and Gd) charge-density-wave (CDW) compounds by optical methods. From the absorption spectrum we extract the excitation energy of the CDW gap and estimate the fraction of the Fermi surface which is gapped by the formation of the CDW condensate. In analogy to previous findings on the related $R$Te$_n$ (n=2 and 3) families, we establish the progressive closing of the CDW gap and the moderate enhancement of the metallic component upon chemically compressing the lattice.
We report the pressure dependence of the optical response of LaTe$_2$, which is deep in the charge-density-wave (CDW) ground state even at 300 K. The reflectivity spectrum is collected in the mid-infrared spectral range at room temperature and at pressures between 0 and 7 GPa. We extract the energy scale due to the single particle excitation across the CDW gap and the Drude weight. We establish that the gap decreases upon compressing the lattice, while the Drude weight increases. This signals a reduction in the quality of nesting upon applying pressure, therefore inducing a lesser impact of the CDW condensate on the electronic properties of LaTe$_2$. The consequent suppression of the CDW gap leads to a release of additional charge carriers, manifested by the shift of weight from the gap feature into the metallic component of the optical response. On the contrary, the power-law behavior, seen in the optical conductivity at energies above the gap excitation and indicating a weakly interacting limit within the Tomonaga-Luttinger liquid scenario, seems to be only moderately dependent on pressure.
We report results of a magneto-optical investigation of the Zintl-phase compound EuIn$_2$P$_2$. The compound orders magnetically at $T_C$=24 K and exhibits concomitant large magnetoresistance effects. For $Tle$50 K and increasing magnetic fields we observe a transfer of spectral weight in $sigma_1(omega)$ from energies above 1 eV into the low-energy metallic component as well as into a mid-infrared signal centered at about 600 cm$^{-1}$. This latter absorption is reminiscent to what has been seen in a large variety of so-called Kondo materials and ascribed to excitations across the hybridization gap. The observed gain of Drude weight upon increasing magnetic field suggests an enhancement of the itinerant charge-carrier concentration due to the increasing magnetization, a phenomenon that was previously observed in other compounds which exhibit colossal magnetoresistive effects.
