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Wetting Phase Transition at the Surface of Liquid Ga-Bi alloys: An X-ray Reflectivity Study

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 نشر من قبل Oleg Shpyrko
 تاريخ النشر 2004
  مجال البحث فيزياء
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X-ray reflectivity measurements of the binary liquid Ga-Bi alloy reveal a dramatically different surface structure above and below the monotectic temperature $T_{mono}=222^{circ}$ C. A Gibbs-adsorbed Bi monolayer resides at the surface at both regimes. However, a 30 {AA} thick, Bi-rich wetting film intrudes between the Bi monolayer and the Ga-rich bulk for $T > T_{mono}$. The internal structure of the wetting film is determined with {AA} resolution, showing a theoretically unexpected concentration gradient and a highly diffuse interface with the bulk phase.



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