Quantum anomalies lead to finite expectation values that defy the apparent symmetries of a system. These anomalies are at the heart of topological effects in fundamental, electronic, photonic and ultracold atomic systems, where they result in a unique response to external fields but generally escape a more direct observation. Here, we implement an optical-network realization of a topological discrete-time quantum walk (DTQW), which we design so that such an anomaly can be observed directly in the unique circular polarization of a topological midgap state. This feature arises in a single-step protocol that combines a chiral symmetry with a previously unexplored unitary version of supersymmetry. Having experimental access to the position and coin state of the walker, we perform a full polarization tomography and provide evidence for the predicted anomaly of the midgap states. This approach opens the prospect to distill topological states dynamically for classical and quantum information applications.
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