The observation is presented of naturally occurring pairing of particles and their cooperative drift in a two-dimensional plasma crystal. A single layer of plastic microspheres was suspended in the plasma sheath of a capacitively coupled rf discharge in argon at a low pressure of 1 Pa. The particle dynamics were studied by combining the top-view and side-view imaging of the suspension. Cross analysis of the particle trajectories allowed us to identify naturally occurring metastable pairs of particles. The lifetime of pairs was long enough for their reliable identification.
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