For the first time, the diffusion phase diagram in highly confined colloidal systems, predicted by Continuous Time Random Walk (CTRW), is experimentally obtained. Temporal and spatial fractional exponents, $alpha$ and $mu$, introduced within the framework of CTRW, are simultaneously measured by Pulse Field Gradient Nuclear Magnetic Resonance technique in samples of micro-beads dispersed in water. We find that $alpha$ depends on the disorder degree of the system. Conversely, $mu$ depends on both bead sizes and magnetic susceptibility differences within samples. Our findings fully match the CTRW predictions.