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Superconductivity and structural properties of Mg1-xAlxB2 materials have been systematically investigated. Evident modifications in both superconductivity and microstructure are identified to originate from the Al ordering along the c-axis direction. The resultant superstructure phase has an optimal composition of MgAlB4 with the superconducting transition at around 12K. Brief diagrams illustrating the superconductivity and structural features of Mg1-xAlxB2 materials along with the increase of Al concentration are presented.
The local structure in high temperature superconductors is nowadays considered a key point for understanding superconductivity mechanism. MgB2 has a well-known simple structure; but its local structure remains quite unexplored. This is due to the fac
Vacancies are prevalent and versatile in solid-state physics and materials science. The role of vacancies in strongly correlated materials, however, remains uncultivated until now. Here, we report the discovery of an unprecedented vacancy state formi
Fermi surface nesting, as a peculiar reciprocal space feature, is not only closely correlated with the real space superstructure, but also directly modulates the underlying electronic behavior. In this work, we elucidate the Fermi surface nesting fea
The physical property characterization of Al doped Mg1-xAlxB2 system with x = 0.0 to 0.50 is reported. The results related to phase formation, structural transition, resistivity R(T) and magnetization M(T) measurements are discussed in detail. It is
Thermoelectric power, S(T) of the Mg1-xAlxB2 system has been measured for x = 0.0, 0.1, 0.2, 0.4, 0.6, 0.8 and 1.0. XRD, resistivity and magnetization measurements are also presented. It has been found that the thermoelectric power is positive for x