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The scales of the white Cyphochilus beetles are endowed with unusual whiteness arising from the exceptional scattering efficiency of their disordered ultrastructure optimized through millions of years of evolution. Here, a simple, one-step method based on water vapor-induced phase separation (VIPS) is developed to prepare ultra-thin polystyrene (PS) films with similar microstructure and comparable optical performance. A typical biomimetic 3.5 um PS film exhibits a diffuse reflectance of 61% at 500 nm, which translates into a transport mean free path below 1 um. A complete optical characterization through Monte Carlo simulations reveals how such scattering performance arises from the scattering coefficient and scattering anisotropy, whose interplay provides insight into the morphological properties of the material. The potential of bright-white coatings as smart sensors or wearable devices is highlighted using a treated ultra-thin film as a real-time sensor for human exhalation.
The microscopic orientation and position of photoactive molecules is crucial to the operation of optoelectronic devices such as OLEDs and solar cells. Here, we introduce a shape-persistent macrocyclic molecule as an excellent fluorescent probe to sim
We study liquid-vapor phase separation under shear via the Shan-Chen lattice Boltzmann model. Besides the rheological characteristics, we analyze the Kelvin-Helmholtz(K-H) instability resulting from the tangential velocity difference of the fluids on
The performance of solution-processed solar cells strongly depends on the geometrical structure and roughness of the photovoltaic layers formed during film drying. During the drying process, the interplay of crystallization and liquid-liquid demixing
Cells possess non-membrane-bound bodies, many of which are now understood as phase-separated condensates. One class of such condensates is composed of two polymer species, where each consists of repeated binding sites that interact in a one-to-one fa
The objective of this work is to study the role of shear on the rupture of ultrathin polymer films. To do so, a finite-difference numerical scheme for the resolution of the thin film equation was set up taking into account capillary and van der Waals