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A model of dipolar dimer liquid (DDL) on a two-dimensional lattice has been proposed. We found that at high density and low temperature, it has a partially ordered phase which we called glacia phase. The glacia phase transition can be understood by mapping the DDL to an annealed Ising model on random graphs. In the high density limit the critical temperature obtained by the Monte Carlo simulation is $k_BT_c^G = (3.5pm0.1)J$, which agrees with the estimations of the upper and lower bounds of $k_BT_c^G$ with exactly solved Ising models. In the high density and low temperature limit, we further studied configurational entropy of the DDL in the presence of the neutral polymers. The suppression of the configurational entropy scales as a power law of the polymer length $lambda_p^alpha$ with $alpha geq 1$, which implies that the configurational entropy of water plays essential roles in understanding the hydrophobic effect and the protein folding problem.
Liquid-liquid phase separation of liquids exhibiting interconversion between alternative states has been proposed as an underlying mechanism for fluid polyamorphism, and may be of relevance to protein function and intracellular organization. However,
We study the dynamical behavior of a square lattice Ising model with exchange and dipolar interactions by means of Monte Carlo simulations. After a sudden quench to low temperatures we find that the system may undergo a coarsening process where strip
Spherical truncations of Coulomb interactions in standard models for water permit efficient molecular simulations and can give remarkably accurate results for the structure of the uniform liquid. However truncations are known to produce significant e
We demonstrate the accurate calculation of entropies and free energies for a variety of liquid metals using an extension of the two phase thermodynamic (2PT) model based on a decomposition of the velocity autocorrelation function into gas-like (hard
The curvature dependence of interfacial free energy, which is crucial in quantitatively predicting nucleation kinetics and the stability of bubbles and droplets, can be described in terms of the Tolman length {delta}. For solid-liquid interfaces, how