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We have determined the superconducting and magnetic properties of four samples of Lu$_x$Zr$_{1-x}$B$_{12}$ ($x=0.04$, $0.07$, $0.17$, and $0.8$) using muon spin rotation ($mu$SR) and magnetometry measurements. We observed a strong magnetic signal in both the $mu$SR and magnetometry data in one sample ($x=0.07$), likely caused by the formation of static moments of size $approx 1,mu_{rm B}$ due to a clustering effect of the Lu$^{3+}$ ions. In all other samples, we find only a small magnetic signal in the $mu$SR data thought to originate from boron nuclei in the B$_{12}$ cages. The superconductivity is found to evolve with $x$, with a decrease in $x$ resulting in an increase in critical temperature and a decrease of the penetration depth. Most remarkably, we find the formation of nodes in the superconducting gap for $x leq 0.17$, providing a new example of an $s$-to-$d$-wave crossover in a superconductor.
Lutetium dodecaboride LuB12 is a simple weak-coupling BCS superconductor with critical temperature Tc = 0.42 K, whilst ZrB12 is a strong-coupling BCS superconductor with the highest critical temperature Tc = 6.0 K among this group of materials. In ca
Based on low temperature resistivity, heat capacity and magnetization investigations we show that the unusually strong suppression of superconductivity in Lu$_x$Zr$_{1-x}$B$_{12}$ BSC-type superconductors in the range $x$$<$0.08 is caused by the emer
The BCS-BEC crossover from strongly overlapping Cooper pairs to non-overlapping composite bosons in the strong coupling limit has been a long-standing issue of interacting many-body fermion systems. Recently, FeSe semimetal with hole and electron ban
The binary Re$_{1-x}$Mo$_x$ alloys, known to cover the full range of solid solutions, were successfully synthesized and their crystal structures and physical properties investigated via powder x-ray diffraction, electrical resistivity, magnetic susce
The Pr-rich end of the alloy series Pr$_{1-x}$Nd$_x$Os$_4$Sb$_{12}$ has been studied using muon spin rotation and relaxation. The end compound PrOs$_4$Sb$_{12}$ is an unconventional heavy-fermion superconductor, which exhibits a spontaneous magnetic