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In the orthorhombic manganites o-RMnO3, where R is a heavy rare earth (R = Gd-Yb), the Mn3+ sublattice is known to undergo two magnetic transitions. The low temperature phase has an antiferromagnetic structure (collinear or elliptical), which has been well characterized by neutron diffraction in most of these compounds. The intermediate phase, occurring in a narrow temperature range (a few K), is documented for R = Gd-Ho as a collinear modulated structure, incommensurate with the lattice spacings. We report here on a 57Fe Mossbauer study of 2% 57Fe doped o-YbMnO3, where the spin only Fe3+ ion plays the role of a magnetic probe. From the analysis of the shape of the magnetic hyperfine Mossbauer spectra, we show that the magnetic structure of the intermediate phase in o-YbMnO3 (38.0 K < T < 41.5 K) is also modulated and incommensurate.
The Fe(1+x)Sb compound has been synthesized close to stoichiometry with x = 0.023(8). The compound was investigated by 57Fe Mossbauer spectroscopy in the temperature range 4.2 - 300 K. The antiferromagnetic ordering temperature was found as 232 K i.e
We present a 57Fe Mossbauer spectroscopy study of the two incommensurate magnetic phases in the multiferroic material FeVO4. We devise lineshapes appropriate for planar elliptical and collinear modulated magnetic structures and show that they reprodu
57Fe Mossbauer spectroscopy measurements were performed on a powdered CuFe2Ge2 sample that orders antiferromagnetically at ~ 175 K. Whereas a paramagnetic doublet was observed above the Neel temperature, a superposition of paramagnetic doublet and ma
The experimental study of the modulation of the envelope of spin-echo signals due to internal and external fields is an important spectroscopic tool to detect very small internal magnetic fields. We derive the free induction decay and the frequency s
By combining dielectric, specific heat, and magnetization measurements and high-resolution neutron powder diffraction, we have investigated the thermodynamic and magnetic/structural properties of the metastable orthorhombic perovskite ErMnO_3 prepare