We present spectroscopic measurements of the Rossiter-McLaughlin effect for the planet b of Kepler-9 multi-transiting planet system. The resulting sky-projected spin-orbit angle is $lambda=-13^{circ} pm 16^{circ}$, which favors an aligned system and strongly disfavors highly misaligned, polar, and retrograde orbits. Including Kepler-9, there are now a total of 4 Rossiter-McLaughlin effect measurements for multiplanet systems, all of which are consistent with spin-orbit alignment.