We present the results from a broadband (1 to 3 GHz), spectro-polarimetry study of the integrated emission from 100 extragalactic radio sources with the ATCA, selected to be highly linearly polarized at 1.4 GHz. We use a general purpose, polarization model-fitting procedure that describes the Faraday rotation measure (RM) and intrinsic polarization structure of up to three distinct polarized emission regions or RM components of a source. Overall, 37%/52%/11% of sources are best fit by one/two/three RM components. However, these fractions are dependent on the signal-to-noise ratio (S/N) in polarization (more RM components more likely at higher S/N). In general, our analysis shows that sources with high integrated degrees of polarization at 1.4 GHz have low Faraday depolarization, are typically dominated by a single RM component, have a steep spectral index, and a high intrinsic degree of polarization. After classifying our sample into radiative-mode and jet-mode AGN, we find no significant difference between the Faraday rotation or Faraday depolarization properties of jet-mode and radiative-mode AGN. However, there is a statistically significant difference in the intrinsic degree of polarization between the two types, with the jet-mode sources having more intrinsically ordered magnetic field structures than the radiative-mode sources. We also find a preferred perpendicular orientation of the intrinsic magnetic field structure of jet-mode AGN with respect to the jet direction, while no clear preference is found for the radiative-mode sources.
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