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For the Fe-based superconductor Fe{1+y}Te{1-x}S{x}, superconductivity is induced by annealing treatment in oxygen atmosphere, whereas as-grown samples do not show superconductivity. We have investigated the sample-size dependence of O2-annealing effects in Fe1.01Te0.91S0.09. The annealing conditions are fixed to be 1 atm, 200 C, and 2 hours. We have carried out magnetic susceptibility and specific heat measurements in order to evaluate the superconducting volume fraction. We have found that Fe{1+y}Te{1-x}S{x} has an optimal size for the induction of bulk superconductivity by O2 annealing. Our results indicate that O2 annealing is probably effective near the surface of samples over a length of a few tens of micro meters.
Recent investigations have shown that Fe$_{1+y}$Te$_{1-x}$Se$_{x}$ can be made superconducting by annealing it in Se and O vapors. The current lore is that these chalcogen vapors induce superconductivity by removing the magnetic excess Fe atoms. To i
Neutron scattering has played a significant role in characterizing magnetic and structural correlations in Fe$_{1+y}$Te$_{1-x}$Se$_x$ and their connections with superconductivity. Here we review several key aspects of the physics of iron chalcogenide
The iron chalcogenide Fe$_{1+y}$Te$_{1-x}$Se$_{x}$ on the Te-rich side is known to exhibit the strongest electron correlations among the Fe-based superconductors, and is non-superconducting for $x$ < 0.1. In order to understand the origin of such beh
The idea of employing non-Abelian statistics for error-free quantum computing ignited interest in recent reports of topological surface superconductivity and Majorana zero modes (MZMs) in FeTe$_{0.55}$Se$_{0.45}$. An associated puzzle is that the top
It has been clarified that bulk superconductivity in Fe$_{1+y}$Te$_{0.6}$Se$_{0.4}$ can be induced by annealing in an appropriate atmosphere to remove the harmful effects of excess iron. In order to clarify the details of the annealing process, we st