We report the first detection of thermal X-ray line emission from the supernova remnant (SNR) RX J1713.7-3946, the prototype of the small class of synchrotron dominated SNRs. A softness-ratio map generated using XMM-Newton data shows that faint interior regions are softer than bright shell regions. Using Suzaku and deep XMM-Newton observations, we have extracted X-ray spectra from the softest area, finding clear line features at 1 keV and 1.35 keV. These lines can be best explained as Ne Ly-alpha and Mg He-alpha from a thermal emission component. Since the abundance ratios of metals to Fe are much higher than solar values in the thermal component, we attribute the thermal emission to reverse-shocked SN ejecta. The measured Mg/Ne, Si/Ne, and Fe/Ne ratios of 2.0-2.6, 1.5-2.0, and <0.05 solar suggest that the progenitor star of RX J1713.7-3946 was a relatively low-mass star (<~20 M_sun), consistent with a previous inference based on the effect of stellar winds of the progenitor star on the surrounding medium. Since the mean blastwave speed of ~6000 km/s (the radius of 9.6 pc divided by the age of 1600 yr) is relatively fast compared with other core-collapse SNRs, we propose that RX J1713.7-3946 is a result of a Type Ib/c supernova whose progenitor was a member of an interacting binary. While our analysis provides strong evidence for X-ray line emission, our interpretation of its nature as thermal emission from SN ejecta requires further confirmation especially through future precision spectroscopic measurements using ASTRO-H.