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We study deuterium fractionation in two massive starless/early-stage cores C1-N and C1-S in Infrared Dark Cloud (IRDC) G028.37+00.07, first identified by Tan et al. (2013) with ALMA. Line emission from multiple transitions of $rm N_2H^+$ and $rm N_2D^+$ were observed with the ALMA, CARMA, SMA, JCMT, NRO 45m and IRAM 30m telescopes. By simultaneously fitting the spectra, we estimate the excitation conditions and deuterium fraction, $D_{rm frac}^{rm N_2H^+} equiv [rm N_2D^+]/[N_2H^+]$, with values of $D_{rm frac}^{rm N_2H^+} simeq 0.2$--$0.7$, several orders of magnitude above the cosmic [D]/[H] ratio. Additional observations of o-H$_2$D$^+$ are also presented that help constrain the ortho-to-para ratio of $rm H_2$, which is a key quantity affecting the degree of deuteration. We then present chemodynamical modeling of the two cores, exploring especially the implications for the collapse rate relative to free-fall, $alpha_{rm ff}$. In order to reach the high level of observed deuteration of $rm N_2H^+$, we find that the most likely evolutionary history of the cores involves collapse at a relatively slow rate, $lesssim1/10$th of free-fall.
We constructed two new models for deuterium and spin-state chemistry for the purpose of modeling the low-temperature environment prevailing in starless and pre-stellar cores. The fundamental difference between the two models is in the treatment of io
How do stars that are more massive than the Sun form, and thus how is the stellar initial mass function (IMF) established? Such intermediate- and high-mass stars may be born from relatively massive pre-stellar gas cores, which are more massive than t
High levels of deuterium fractionation of $rm N_2H^+$ (i.e., $rm D_{frac}^{N_2H^+} gtrsim 0.1$) are often observed in pre-stellar cores (PSCs) and detection of $rm N_2D^+$ is a promising method to identify elusive massive PSCs. However, the physical
We carry out an ALMA $rm N_2D^+$(3-2) and 1.3~mm continuum survey towards 32 high mass surface density regions in seven Infrared Dark Clouds with the aim of finding massive starless cores, which may be the initial conditions for the formation of mass
We present the results of a single-pointing survey of 207 dense cores embedded in Planck Galactic Cold Clumps distributed in five different environments ($lambda$ Orionis, Orion A, B, Galactic plane, and high latitudes) to identify dense cores on the