A new scheme for bright hard x-ray emission from laser wakefield electron accelerator is reported, where pure nitrogen gas is adopted. Intense Betatron x-ray beams are generated from ionization injected K-shell electrons of nitrogen into the accelerating wave bucket. The x-ray radiation shows synchrotron-like spectrum with total photon yield 8$times$10$^8$/shot and $10^8$ over 110keV. In particular, the betatron hard x-ray photon yield is 10 times higher compared to the case of helium gas under the same laser parameters. Particle-in-cell simulation suggests that the enhancement of the x-ray yield results from ionization injection, which enables the electrons to be quickly accelerated to the driving laser region for subsequent betatron resonance. Employing the present scheme,the single stage nitrogen gas target could be used to generate stable high brightness betatron hard x-ray beams.
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