اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدStationary points approach to thermodynamic phase transitions
101
0
0.0
(
0
)
تأليف
Michael Kastner
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
Nonanalyticities of thermodynamic functions are studied by adopting an approach based on stationary points of the potential energy. For finite systems, each stationary point is found to cause a nonanalyticity in the microcanonical entropy, and the functional form of this nonanalytic term is derived explicitly. With increasing system size, the order of the nonanalytic term grows, leading to an increasing differentiability of the entropy. It is found that only asymptotically flat stationary points may cause a nonanalyticity that survives in the thermodynamic limit, and this property is used to derive an analytic criterion establishing the existence or absence of phase transitions. We sketch how this result can be employed to analytically compute transition energies of classical spin models.
قيم البحث
اقرأ أيضاً
We construct a novel approach, based on thermodynamic geometry, to characterize first-order phase transitions from a microscopic perspective, through the scalar curvature in the equilibrium thermodynamic state space. Our method resolves key theoretic
al issues in macroscopic thermodynamic constructs, and furthermore characterizes the Widom line through the maxima of the correlation length, which is captured by the thermodynamic scalar curvature. As an illustration of our method, we use it in conjunction with the mean field Van der Waals equation of state to predict the coexistence curve and the Widom line. Where closely applicable, it provides excellent agreement with experimental data. The universality of our method is indicated by direct calculations from the NIST database.
We present some aspects of the fidelity approach to phase transitions based on lower and upper bounds on the fidelity susceptibility that are expressed in terms of thermodynamic quantities. Both commutative and non commutative cases are considered. I
n the commutative case, in addition, a relation between the fidelity and the nonequilibrium work done on the system in a process from an equilibrium initial state to an equilibrium final state has been obtained by using the Jarzynski equality.
We present a study of phase transitions of the Curie--Weiss Potts model at (inverse) temperature $beta$, in presence of an external field $h$. Both thermodynamic and topological aspects of these transitions are considered. For the first aspect we com
plement previous results and give an explicit equation of the thermodynamic transition line in the $beta$--$h$ plane as well as the magnitude of the jump of the magnetization (for $q geqslant 3)$. The signature of the latter aspect is characterized here by the presence or not of a giant component in the clusters of a Fortuin--Kasteleyn type representation of the model. We give the equation of the Kertesz line separating (in the $beta$--$h$ plane) the two behaviours. As a result, we get that this line exhibits, as soon as $q geqslant 3$, a very interesting cusp where it separates from the thermodynamic transition line.
We study the response to perturbations in the thermodynamic limit of a network of coupled identical agents undergoing a stochastic evolution which, in general, describes non-equilibrium conditions. All systems are nudged towards the common centre of
mass. We derive Kramers-Kronig relations and sum rules for the linear susceptibilities obtained through mean field Fokker-Planck equations and then propose corrections relevant for the macroscopic case, which incorporates in a self-consistent way the effect of the mutual interaction between the systems. Such an interaction creates a memory effect. We are able to derive conditions determining the occurrence of phase transitions specifically due to system-to-system interactions. Such phase transitions exist in the thermodynamic limit and are associated with the divergence of the linear response but are not accompanied by the divergence in the integrated autocorrelation time for a suitably defined observable. We clarify that such endogenous phase transitions are fundamentally different from other pathologies in the linear response that can be framed in the context of critical transitions. Finally, we show how our results can elucidate the properties of the Desai-Zwanzig model and of the Bonilla-Casado-Morillo model, which feature paradigmatic equilibrium and non-equilibrium phase transitions, respectively.
We analytically and numerically study the Loschmidt echo and the dynamical order parameters in a spin chain with a deconfined phase transition between a dimerized state and a ferromagnetic phase. For quenches from a dimerized state to a ferromagnetic
phase, we find that the model can exhibit a dynamical quantum phase transition characterized by an associating dimerized order parameters. In particular, when quenching the system from the Majumdar-Ghosh state to the ferromagnetic Ising state, we find an exact mapping into the classical Ising chain for a quench from the paramagnetic phase to the classical Ising phase by analytically calculating the Loschmidt echo and the dynamical order parameters. By contrast, for quenches from a ferromagnetic state to a dimerized state, the system relaxes very fast so that the dynamical quantum transition may only exist in a short time scale. We reveal that the dynamical quantum phase transition can occur in systems with two broken symmetry phases and the quench dynamics may be independent on equilibrium phase transitions.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
