In the next decade Type Ia supernovae (SNe Ia) will be used to test theories predicting changes in the Dark Energy equation of state with time. Ultimately this requires a dedicated space mission like JDEM. SNe Ia are mature cosmological probes --- their limitations are well characterized, and a path to improvement is clear. Dominant systematic errors include photometric calibration, selection effects, reddening, and population-dependent differences. Building on past lessons, well-controlled new surveys are poised to make strides in these areas: the Palomar Transient Factory, Skymapper, La Silla QUEST, Pan-STARRS, the Dark Energy Survey, LSST, and JDEM. They will obviate historical calibrations and selection biases, and allow comparisons via large subsamples. Some systematics follow from our ignorance of SN Ia progenitors, which there is hope of determining with SN Ia rate studies from 0<z<4. Aside from cosmology, SNe Ia regulate galactic and cluster chemical evolution, inform stellar evolution, and are laboratories for extreme physics. Essential probes of SNe Ia in these contexts include spectroscopy from the UV to the IR, X-ray cluster and SN remnant observations, spectropolarimetry, and advanced theoretical studies. While there are an abundance of discovery facilities planned, there is a deficit of follow-up resources. Living in the systematics era demands deep understanding rather than larger statistics. NOAO ReSTAR initiative to build 2-4m telescopes would provide necessary follow-up capability. Finally, to fully exploit LSST, well-matched wide-field spectroscopic capabilities are desirable.
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