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Inelastic x-ray scattering (IXS) measurements of the dynamic structure factor in liquid Na57K43, sensitive to the atomic-scale coarse graining, reveal a sound velocity value exceeding the long wavelength, continuum value and indicate the coexistence of two phonon-like modes. Applying Generalized Collective Mode (GCM) analysis scheme, we show that the positive dispersion of the sound velocity occurs in a wavelength region below the crossover from hydrodynamic to atom-type excitations and, therefore, it can not be explained as sound propagation over the light specie (Na) network. The present result experimentally proves the existence of positive dispersion in a binary mixture due to a relaxation process, as opposed to fast sound phenomena.
Surface sensitive x-ray scattering techniques with atomic scale resolution are employed to investigate the microscopic structure of the surface of three classes of liquid binary alloys: (i) Surface segregation in partly miscible binary alloys as pred
Measurements of the surface x-ray scattering from several pure liquid metals (Hg, Ga, and In) and from three alloys (Ga-Bi, Bi-In, and K-Na) with different heteroatomic chemical interactions in the bulk phase are reviewed. Surface-induced layering is
We show, that the theoretical expression for the dispersion of collective excitations reported in [Phys. Rev. B {bf 103}, 099901 (2021)], at variance with what was claimed in the paper, does not account for the energy fluctuations and does not tend i
We show that the presented in Phys.Rev.B, v.101, 214312 (2020) theoretical expressions for longitudinal current spectral function $C^L(k,omega)$ and dispersion of collective excitations are not correct. Indeed, they are not compatible with the contin
Tunnelling Two-Level Systems (TLS) dominate the physics of glasses at low temperatures. Yet TLS are extremely rare and it is extremely difficult to directly observe them $it{in , silico}$. It is thus crucial to develop simple structural predictors th