Rotation has become an important element in evolutionary models of massive stars, specifically via the prediction of rotational mixing. Here, we study a sample of stars, including rapid rotators, to constrain such models and use nitrogen enrichments as a probe of the mixing process. Chemical compositions (C, N, O, Mg and Si) have been estimated for 135 early B-type stars in the Large Magellanic Cloud with projected rotational velocities up to ~300km/s using a non-LTE TLUSTY model atmosphere grid. Evolutionary models, including rotational mixing, have been generated attempting to reproduce these observations by adjusting the overshooting and rotational mixing parameters and produce reasonable agreement with 60% of our core hydrogen burning sample. We find (excluding known binaries) a significant population of highly nitrogen enriched intrinsic slow rotators vsini less than 50km/s incompatible with our models ~20% of the sample). Furthermore, while we find fast rotators with enrichments in agreement with the models, the observation of evolved (log g less than 3.7dex) fast rotators that are relatively unenriched (a further ~20% of the sample) challenges the concept of rotational mixing. We also find that 70% of our blue supergiant sample cannot have evolved directly from the hydrogen burning main-sequence. We are left with a picture where invoking binarity and perhaps fossil magnetic fields are required to understand the surface properties of a population of massive main sequence stars.
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