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Bright HNC 1--0 emission has been found towards several Seyfert galaxies. This is unexpected since traditionally HNC is a tracer of cold (10 K) gas, and the molecular gas of luminous galaxies like Seyferts is thought to have bulk kinetic temperatures surpassing 50 K. In this work we aim to distinguish the cause of the bright HNC and to model the physical conditions of the HNC and HCN emitting gas. We have used SEST, JCMT and IRAM 30m telescopes to observe HNC 3-2 and HCN 3-2 line emission in a selection of 5 HNC-luminous Seyfert galaxies. We estimate and discuss the excitation conditions of HCN and HNC in NGC 1068, NGC 3079, NGC 2623 and NGC 7469, based on the observed 3-2/1-0 line intensity ratios. We also observed CN 1-0 and 2-1 emission and discuss its role in photon and X-ray dominated regions. HNC 3-2 was detected in 3 galaxies (NGC 3079, NGC 1068 and NGC 2623). HCN 3-2 was detected in NGC 3079, NGC 1068 and NGC 1365. The HCN 3-2/1-0 ratio is lower than 0.3 only in NGC 3079, whereas the HNC 3-2/1-0 ratio is larger than 0.3 only in NGC 2623. The HCN/HNC 1-0 and 3-2 line ratios are larger than unity in all the galaxies. The HCN/HNC 3-2 line ratio is lower than unity only in NGC 2623, similar to Arp 220, Mrk 231 and NGC 4418. In three of the galaxies the HNC emissions emerge from gas of densities n<10^5 cm^3, where the chemistry is dominated by ion-neutral reactions. In NGC 1068 the emission of HNC emerges from lower (<10^5 cm^3) density gas than HCN (>10^5 cm^3). Instead, the emissions of HNC and HCN emerge from the same gas in NGC 3079. The observed HCN/HNC and CN/HCN line ratios favor a PDR scenario, rather than an XDR one. However, the N(HNC)/N(HCN) column density ratios obtained for NGC 3079 can be found only in XDR environments.
Aims. The comparative study of several molecular species at the origin of the gas phase chemistry in the diffuse interstellar medium (ISM) is a key input in unraveling the coupled chemical and dynamical evolution of the ISM. Methods. The lowest rotat
HNC and HCN, typically used as dense gas tracers in molecular clouds, are a pair of isomers that have great potential as a temperature probe because of temperature dependent, isomer-specific formation and destruction pathways. Previous observations o
We build an accurate database of 5200 HCN and HNC rotation-vibration energy levels, determined from existing laboratory data. 20~000 energy levels in the Harris et al. (2002) linelist are assigned approximate quantum numbers. These assignments, lab d
HCN and its isomer HNC play an important role in molecular cloud chemistry and the formation of more complex molecules. We investigate here the impact of protostellar shocks on the HCN and HNC abundances from high-sensitivity IRAM 30m observations of
We use both new and archival ALMA data of three energy lines each of CN and HCN to explore intensity ratios in dense gas in NGC 3256, NGC 7469, and IRAS 13120-5453. The HCN (3-2)/HCN (1-0) intensity ratio varies in NGC 3256 and NGC 7469, with superli