ترغب بنشر مسار تعليمي؟ اضغط هنا

Direct link between low temperature magnetism and high temperature sodium order in NaxCoO2

95   0   0.0 ( 0 )
 نشر من قبل Tim Schulze
 تاريخ النشر 2007
  مجال البحث فيزياء
والبحث باللغة English
 تأليف T. F. Schulze




اسأل ChatGPT حول البحث

We prove the direct link between low temperature magnetism and high temperature sodium ordering in NaxCoO2 using the example of a heretofore unreported magnetic transition at 8 K which involves a weak ferromagnetic moment. The 8 K feature is characterized in detail and its dependence on a diffusive sodium rearrangement around 200 K is demonstrated. Applying muons as local probes this process is shown to result in a reversible phase separation into distinct magnetic phases that can be controlled by specific cooling protocols. Thus the impact of ordered sodium Coulomb potential on the CoO2 physics is evidenced opening new ways to experimentally revisit the NaxCoO2 phase diagram.



قيم البحث

اقرأ أيضاً

We report a systematic study of the $c$ lattice parameter in the Na$_{x}$CoO$_{2}$ phases versus Na content $x>0.5$, in which sodium always displays ordered arrangements. This allows us to single out the first phase which exhibits an AF magnetic orde r at a Neel temperature $T_{N}=$22 K which is found to occur for $xapprox 0.77(1)$. Pure samples of this phase have been studied both as aligned powders and single crystals. They exhibit identical $^{23}$Na NMR spectra in which three sets of Na sites could be fully resolved, and are found to display $T$ dependencies of their NMR shifts which scale with each other. This allows us to establish that the $T$ variation of the shifts is due to the paramagnetism of the Co sites with formal charge state larger than 3$^{+}$. The existence of a sodium site with axial charge symmetry and the intensity ratio between the sets of $^{23}$Na lines permits us to reveal that the 2D structure of the Na order corresponds to 10 Na sites on top of a 13 Co sites unit cell, that is with $x=10/13approx 0.77$. This structure fits with that determined from local density calculations and involves triangles of 3 Na sites located on top of Co sites (so called Na1 sites). The associated ordering of the Na vacancies is quite distinct from that found for $x<0.75$.
119 - Yinghao Zhu , Si Wu , Bao Tu 2020
Magnetization measurements and time-of-flight neutron powder-diffraction studies on the high-temperature (300--980 K) magnetism and crystal structure (321--1200 K) of a pulverized YCrO$_3$ single crystal have been performed. Temperature-dependent inv erse magnetic susceptibility coincides with a piecewise linear function with five regimes, with which we fit a Curie-Weiss law and calculate the frustration factor $f$. The fit results indicate a formation of magnetic polarons between 300 and 540 K and a very strong magnetic frustration. By including one factor $eta$ that represents the degree of spin interactions into the Brillouin function, we can fit well the applied-magnetic-field dependence of magnetization. No structural phase transition was observed from 321 to 1200 K. The average thermal expansions of lattice configurations (emph{a}, emph{b}, emph{c}, and emph{V}) obey well the Gr$ddot{textrm{u}}$neisen approximations with an anomaly appearing around 900 K, implying an isosymmetric structural phase transition, and display an anisotropic character along the crystallographic emph{a}, emph{b}, and emph{c} axes with the incompressibility $K^a_0 > K^c_0 > K^b_0$. It is interesting to find that at 321 K, the local distortion size $Delta$(O2) $approx$ 1.96$Delta$(O1) $approx$ 4.32$Delta$(Y) $approx$ 293.89$Delta$(Cr). Based on the refined Y-O and Cr-O bond lengths, we deduce the local distortion environments and modes of Y, Cr, O1, and O2 ions. Especially, the Y and O2 ions display obvious atomic displacement and charge subduction, which may shed light on the dielectric property of the YCrO$_3$ compound. Additionally, by comparing Kramers Mn$^{3+}$ with non-Kramers Cr$^{3+}$ ions, it is noted that being a Kramers or non-Kramers ion can strongly affect the local distortion size, whereas, it may not be able to change the detailed distortion mode.
New electronic phases have been identified and placed in the (T,H) phase diagram of metallic NaxCoO2. At low Na-content (x = 0.36), the magnetic susceptibility diverges with a power law T^(-n), n<1, and shows (T,H) scaling, indicating the proximity t o a magnetic quantum phase transition. At high Na contents (x = 0.6) the mass of the quasiparticles does never diverge, but renormalizes and becomes strongly field dependent at low temperatures, forming a heavy Fermi-Liquid. Our results make superconducting NaxCoO2 a clear candidate for magnetically mediated pairing.
446 - Y. V. Sushko 2005
The results of DC magnetization measurements under hydrostatic (helium-gas) pressure are reported for an ambient pressure superconductor Na0.35CoO2.1.4D2O and its precursor compound, the gamma-phase Na0.75CoO2 that is known to combine a metallic cond uctivity with an unusual magnetic state below ~22K. The obtained data allowed us to present for the first time the pressure dependence of the magnetic transition in a metallic sodium cobaltate system. This dependence appears to be positive, with the magnetic transition rapidly shifting towards higher temperatures when an applied pressure increases. We ascribe the observed effect to the pressure-induced enhancement of the out-of-plane antiferromagnetic coupling mediated by localized spins interactions (of either superexchange or RKKY type), the scenario consistent with the A-type antiferromagnetic state suggested by recent neutron-scattering data. As for the pressure effect on the superconductivity in Na0.35CoO2.1.4D2O, our measurements established negative and linear for the entire pressure range from 1 bar to 8.3 kbar pressure dependence of Tc, the behavior quite different from the reported by previous workers strong non-linearity of the Tc (P) dependence. (Dated September 12, 2005) PACS numbers: 74.62.Fj, 74.70.-b, 75.20. En, 75.50 Ee, 75.30 Kz.
We report giant thermopower S = 2.5 mV/K in CoSbS single crystals, a material that shows strong high-temperature thermoelectric performance when doped with Ni or Se. Changes of low temperature thermopower induced by magnetic field point to mechanism of electronic diffusion of carriers in the heavy valence band. Intrinsic magnetic susceptibility is consistent with the Kondo- Insulator-like accumulation of electronic states around the gap edges. This suggests that giant thermopower stems from temperature-dependent renormalization of the non-interacting bands and buildup of the electronic correlations on cooling.
التعليقات
جاري جلب التعليقات جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
mircosoft-partner

هل ترغب بارسال اشعارات عن اخر التحديثات في شمرا-اكاديميا