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We discuss the current status of the theory of the high-temperature superconductivity in intercalated graphites YbC6 and CaC6. We emphasize that while the general picture of conventional, phonon-driven superconductivity has already emerged and is generally accepted, there are still interesting problems with this picture, such as weak-coupling regime inferred from specific heat suggesting coupling exclusively with high-energy carbon phonons coming in direct contradiction with the isotope effect measurements suggesting coupling exclusively with the low-energy intercalant modes. At the same time, the first principle calculations, while explaining Tc, contradict both of the experiments above by predicting equal coupling with both groups of phonons.
By means of synchrotron X-ray diffraction, we studied the effect of high pressure, P, up to 13 GPa on the room temperature crystal structure of superconducting CaC6. In this P range, no change of the pristine space group symmetry, textit{R=3m}, is fo
Point-contact tunneling on CaC$_6$ crystals reproducibly reveals superconducting gaps, $Delta$, of 2.3$pm$0.2 meV which are $sim$~40% larger than earlier reports. That puts CaC$_6$ into the class of very strong-coupled superconductors since 2$Delta$/
We show that a recently predicted layered phase of lithium monoboride, Li2B2, combines the key mechanism for strong electron-phonon coupling in MgB2 (i.e., interaction of covalent B sigma bands with B bond-stretching modes) with the dominant coupling
Mg10Ir19B16, a previously unreported compound in the Mg-Ir-B chemical system, is found to be superconducting at temperatures near 5 K. The fact that the compound exhibits a range of superconducting temperatures between 4 and 5 K suggests that a range
Single crystals of the compound LaFePO were prepared using a flux growth technique at high temperatures. Electrical resistivity measurements reveal metallic behavior and a resistive transition to the superconducting state at a critical temperature T_