We extend the Riemann-Hilbert (RH) method to study the inverse scattering transformation and high-order pole solutions of the focusing and defocusing nonlocal (reverse-space-time) modified Korteweg-de Vries (mKdV) equations with nonzero boundary conditions (NZBCs) at infinity and successfully find its multiple soliton solutions with one high-order pole and multiple high-order poles. By introducing the generalized residue formula, we overcome the difficulty caused by calculating the residue conditions corresponding to the higher-order poles. In accordance with the Laurent series of reflection coefficient and oscillation term, the determinant formula of the high-order pole solution with NZBCs is established. Finally, combined with specific parameters, the dynamic propagation behaviors of the high-order pole solutions are further analyzed and some very interesting phenomena are obtained, including kink solution, anti kink solution, rational solution and breathing-soliton solution.