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We present a comparative study of the near-infrared (NIR) H$_2$ line emission from five regions near hot young stars: Sharpless 140, NGC 2023, IC 63, the Horsehead Nebula, and the Orion Bar. This emission originates in photodissociation or photon-dominated regions (PDRs), interfaces between photoionized and molecular gas near hot (O) stars or reflection nebulae illuminated by somewhat cooler (B) stars. In these environments, the dominant excitation mechanism for NIR emission lines originating from excited rotational-vibrational (rovibrational) levels of the ground electronic state is radiative or UV excitation (fluorescence), wherein absorption of far-UV photons pumps H$_2$ molecules into excited electronic states from which they decay into the upper levels of the NIR lines. Our sources span a range of UV radiation fields ($G_0 = 10^2$-$10^5$) and gas densities ($n_H = 10^4$-$10^6$ cm$^{-3}$), enabling examination of how these properties affect the emergent spectrum. We obtained high-resolution ($R approx 45,000$) spectra spanning $1.45$-$2.45$~$mu$m on the 2.7m Harlan J. Smith Telescope at McDonald Observatory with the Immersion Grating INfrared Spectrometer (IGRINS), detecting up to over 170 transitions per source from excited vibrational states ($v = 1$-$14$). The populations of individual rovibrational levels derived from these data clearly confirm UV excitation. Among the five PDRs in our survey, the Orion Bar shows the greatest deviation of the populations and spectrum from pure UV excitation, while Sharpless 140 shows the least deviation. However, we find that all five PDRs exhibit at least some modification of the level populations relative to their values under pure UV excitation, a result we attribute to collisional effects.
We derive total (atomic + molecular) hydrogen densities in giant molecular clouds (GMCs) in the nearby spiral galaxy M33 using a method that views the atomic hydrogen near regions of recent star formation as the product of photodissociation. Far-UV p
Molecular hydrogen is the most abundant molecule in the Universe. It is thought that a large portion of H2 forms by association of hydrogen atoms to polycyclic aromatic hydrocarbons (PAHs). We model the influence of PAHs on total H2 formation rates i
Recent studies have confirmed the presence of buckminsterfullerene (C$_{60}$) in different interstellar and circumstellar environments. However, several aspects regarding C$_{60}$ in space are not well understood yet, such as the formation and excita
We have carried out a near-infrared, narrow-band imaging survey of the Crab Nebula, in the H2 2.12 micron and Br-gamma 2.17 micron lines, using the Spartan Infrared camera on the SOAR Telescope. Over a 2.8 x 5.1 area that encompasses about 2/3 of the
We present a systematic study of the 3.0 um H2O ice and the 3.4 um aliphatic carbon absorption features toward 48 local ultraluminous infrared galaxies (ULIRGs) using spectra obtained by the AKARI Infrared Camera to investigate the UV environment in