We examine the relationship between the singular set of a compact Riemannian orbifold and the spectrum of the Hodge Laplacian on $p$-forms by computing the heat invariants associated to the $p$-spectrum. We show that the heat invariants of the $0$-spectrum together with those of the $1$-spectrum for the corresponding Hodge Laplacians are sufficient to distinguish orbifolds with singularities from manifolds as long as the singular sets have codimension $le 3.$ This is enough to distinguish orbifolds from manifolds for dimension $le 3.$