This Letter investigates the nature of synchronization in multilayered and multiplexed populations in which the interlayer interactions are randomly pinned. First, we show that a multilayer network constructed by setting up all-to-all interlayer connections between the two populations leads to explosive synchronization in the two populations successively, leading to the coexistence of coherent and incoherent populations forming chimera states. Second, a multiplex formation of the two populations in which only the mirror nodes are interconnected espouses explosive transitions in the two populations concurrently. The emergence of explosive synchronization is substantiated with rigorous mean-field calculations demonstrating the existence of a bistable region. The random pinning in the interlayer interactions concerns the practical problems where the impact of dynamics of one network on that of other interconnected networks remains elusive, as is the case for many real-world systems.
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