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Precursor phenomena observed prior to the martensite phase transition plays a critical role towards the understanding of important technological properties of shape memory and magnetic shape memory alloys (MSMAs). The premartensite (PM) phase, considered as the precursor state of the martensite is proven to be a thermodynamically stable phase recently (Nature Commun. 8, 1006 (2017)), necessitates a critical investigation of precursor effects in these materials. We present here an evidence for the existence of a precursor state of the PM phase in Ni2MnGa MSMA using high energy synchrotron pair distribution function (PDF) study. The precursor state embedded within the austenite matrix in the short-range ordered (SRO) regime starting from far above the actual PM phase transition. The presence of such SRO precursor states of the PM phase produces strains which couple with the ferromagnetic (FM) order parameter around TC leading to first order character of the paramagnetic to FM phase transition.
The premartensite phase of shape memory and magnetic shape memory alloys (MSMAs) is believed to be a precursor state of the martensite phase with preserved austenite phase symmetry. The thermodynamic stability of the premartensite phase and its relat
An inelastic neutron scattering study of the lattice dynamics of the martensite phase of the ferromagnetic shape memory alloy, Ni2MnGa, reveals the presence of well-defined phasons associated with the charge density wave (CDW) resulting from Fermi su
The origin of incommensurate structural modulation in Ni-Mn based Heusler type magnetic shape memory alloys (MSMAs) is still an unresolved issue inspite of intense focus on this due to its role in the magnetic field induced ultra-high strains. In the
We predict the existence of a new ferromagnetic shape memory alloy Ga_2MnNi using density functional theory. The martensitic start temperature (T_M) is found to be approximately proportional to the stabilization energy of the martensitic phase (delta
Magnetic shape memory Heusler alloys are multiferroics stabilized by the correlations between electronic, magnetic and structural order. To study these correlations we use time resolved x-ray diffraction and magneto-optical Kerr effect experiments to