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We present a theoretical calculation of the influence of ultraviolet radiative pumping on the excitation of the rotational levels of the ground vibrational state for HD molecules under conditions of the cold diffuse interstellar medium (ISM). Two main excitation mechanisms have been taken into account in our analysis: (i) collisions with atoms and molecules and (ii) radiative pumping by the interstellar ultraviolet (UV) radiation field. The calculation of the radiative pumping rate coefficients $Gamma_{rm ij}$ corresponding to Dranes model of the field of interstellar UV radiation, taking into account the self-shielding of HD molecules, is performed. We found that the population of the first HD rotational level ($J = 1$) is determined mainly by radiative pumping rather than by collisions if the thermal gas pressure $p_{rm th}le10^4left(frac{I_{rm{UV}}}{1}right),mbox{K,cm}^{-3}$ and the column density of HD is lower than $log N({rm{HD}})<15$. Under this constraint the populations of rotational levels of HD turns out to be as well a more sensitive indicator of the UV radiation intensity than the fine-structure levels of atomic carbon. We suggest that taking into account radiative pumping of HD rotational levels may be important for the problem of the cooling of primordial gas at high redshift: ultraviolet radiation from first stars can increase the rate of HD cooling of the primordial gas in the early Universe.
We study the behavior of eight diffuse interstellar bands (DIBs) in different interstellar environments, as characterized by the fraction of hydrogen in molecular form [$f$(H$_2$)], with comparisons to the corresponding behavior of various known atom
We present a general parameter study, in which the abundance of interstellar argonium (ArH$^+$) is predicted using a model for the physics and chemistry of diffuse interstellar gas clouds. Results have been obtained as a function of UV radiation fiel
We investigate one mechanism of the change in the isotopic composition of cosmologically distant clouds of interstellar gas whose matter was subjected only slightly to star formation processes. According to the standard cosmological model, the isotop
We present a comprehensive analysis of interstellar absorption lines seen in moderately-high resolution, high signal-to-noise ratio optical spectra of SN 2014J in M82. Our observations were acquired over the course of six nights, covering the period
We present a systematic study of deuterated molecular hydrogen (HD) at high redshift, detected in absorption in the spectra of quasars. We present four new identifications of HD lines associated with known $rm H_2$-bearing Damped Lyman-$alpha$ system