The phenomenon of spontaneous scalarization of Reissner-Nordstr{o}m (RN) black holes has recently been found in an Einstein-Maxwell-scalar (EMS) model due to a non-minimal coupling between the scalar and Maxwell fields. Non-linear electrodynamics, e.g., Born-Infeld (BI) electrodynamics, generalizes Maxwells theory in the strong field regime. Non-minimally coupling the BI field to the scalar field, we study spontaneous scalarization of an Einstein-Born-Infeld-scalar (EBIS) model in this paper. It shows that there are two types of scalarized black hole solutions, i.e., scalarized RN-like and Schwarzschild-like solutions. Although the behavior of scalarized RN-like solutions in the EBIS model is quite similar to that of scalarize solutions in the EMS model, we find that there exist significant differences between scalarized Schwarzschild-like solutions in the EBIS model and scalarized solutions in the EMS model. In particular, the domain of existence of scalarized Schwarzschild-like solutions possesses a certain region, which is composed of two branches. The branch of larger horizon area is a family of disconnected scalarized solutions, which do not bifurcate from scalar-free black holes. However, the branch of smaller horizon area may or may not bifurcate from scalar-free black holes depending on the parameters. Additionally, these two branches of scalarized solutions can be both entropically disfavored over comparable scalar-free black holes in some parameter region.
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