We investigate an oblique spacetime crystal realized by a monoatomic crystal in which a mode of sound propagates. We provide a systematic analysis of the crystal and obtain the corresponding band structure, based on which the electron dynamics under an external electric field is studied. Several unique band topologies are revealed, which lead to novel Floquet-Bloch oscillations in the electrons motion. We also discover intraband Zener tunneling in the oblique spacetime crystal beyond the adiabatic limit, which effectively converts between the different band topologies. Our results indicate the possibility of a prototypical quantum acoustoelectric generator that converts energy between the sound wave and a DC electric field in quantized units.