It is expected in physics that the homogeneous quantum Boltzmann equation with Fermi-Dirac or Bose-Einstein statistics and with Maxwell-Boltzmann operator (neglecting effect of the statistics) for the weak coupled gases will converge to the homogeneous Fokker-Planck-Landau equation as the Planck constant $hbar$ tends to zero. In this paper and the upcoming work cite{HLP2}, we will provide a mathematical justification on this semi-classical limit. Key ingredients into the proofs are the new framework to catch the {it weak projection gradient}, which is motivated by Villani cite{V1} to identify the $H$-solution for Fokker-Planck-Landau equation, and the symmetric structure inside the cubic terms of the collision operators.