We suggest a new thermodynamic curvature, constructed via adiabatic compressibility, for examining the internal microstructure of charged black holes in an anti-de Sitter (AdS) background. We analyze the microscopic properties of small-large phase transition of black holes with pressure and volume as the fluctuation variables. We observe that strong repulsive interactions dominate among the micro-structures of near extremal small black holes, and the thermodynamic curvature diverges to positive infinity for the extremal black holes. At the critical point, however, thermodynamic curvature diverges to negative infinity.
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