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We study isolated core excitation of ultra cold ytterbium Rydberg atoms of high orbital quantum number. Measurements were performed on the $6s_{1/2} 40l rightarrow 6p_{1/2} 40l $ transition with $l=5-9$. The extracted energy shifts and autoionization rates are in good agreement with a model based on independant electrons, taking into account interactions in a perturbative approach. We reveal a particularly long persistence of the autoionization rates with the orbital quantum number, explained by the strong coupling of the $6p_{1/2}nl$ autoionizing state with the $5d_{3/2}epsilon l$ continua compared to previously studied divalent atoms.
We observe trilobite-like states of ultracold 85Rb2 molecules, in which a ground-state atom is bound by the electronic wavefunction of its Rydberg-atom partner. We populate these states through the ultraviolet excitation of weakly-bound molecules, an
Long-range dipole-dipole and quadrupole-quadrupole interactions between pairs of Rydberg atoms are calculated perturbatively for calcium, strontium and ytterbium within the Coulomb approximation. Quantum defects, obtained by fitting existing laser sp
We study electromagnetically induced transparency (EIT) in the 5s$rightarrow$5p$rightarrow$46s ladder system of a cold $^{87}$Rb gas. We show that the resonant microwave coupling between the 46s and 45p states leads to an Autler-Townes splitting of t
We present quantum mechanical calculations of Auger decay rates for two Rubidium Rydberg atoms with weakly overlapping electron clouds. We neglect exchange effects and consider tensor products of independent atom states forming an approximate basis o
We provide a detailed theoretical and conceptual study of a planned experiment to excite Rydberg states of ions trapped in a Paul trap. The ultimate goal is to exploit the strong state dependent interactions between Rydberg ions to implement quantum