Sources of entangled electromagnetic radiation are a cornerstone in quantum information processing and offer unique opportunities for the study of quantum many-body physics in a controlled experimental setting. While multi-mode entangled states of radiation have been generated in various platforms, all previous experiments are either probabilistic or restricted to generate specific types of states with a moderate entanglement length. Here, we demonstrate the fully deterministic generation of purely photonic entangled states such as the cluster, GHZ, and W state by sequentially emitting microwave photons from a controlled auxiliary system into a waveguide. We tomographically reconstruct the entire quantum many-body state for up to $N=4$ photonic modes and infer the quantum state for even larger $N$ from process tomography. We estimate that localizable entanglement persists over a distance of approximately ten photonic qubits, outperforming any previous deterministic scheme.
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