We investigate the reliability and security of the ambient backscatter (AmBC) non-orthogonal multiple access (NOMA) systems, where the source aims to communication with two NOMA users in the presence of an eavesdropper. We consider a more practical case that nodes and backscatter device (BD) suffer from in-phase and quadrature-phase imbalance (IQI). More specifically, exact analytical expressions for the outage probability (OP) and the intercept probability (IP) are derived in closedform. Moreover, the asymptotic behaviors and corresponding diversity orders for the OP are discussed. Numerical results show that: 1) Although IQI reduces the reliability, it can enhance the security. 2) Compared with the traditional orthogonal multiple access (OMA) system, the AmBC-NOMA system can obtain better reliability when the signal-to-noise (SNR) ratio is low; 3) There are error floors for the OP because of the reflection coefficient b{eta} .
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