This Report summarizes the proceedings of the 2019 Les Houches workshop on Physics at TeV Colliders. Session 1 dealt with (I) new developments for high precision Standard Model calculations, (II) the sensitivity of parton distribution functions to the experimental inputs, (III) new developments in jet substructure techniques and a detailed examination of gluon fragmentation at the LHC, (IV) issues in the theoretical description of the production of Standard Model Higgs bosons and how to relate experimental measurements, and (V) Monte Carlo event generator studies relating to PDF evolution and comparisons of important processes at the LHC.