When the density of a nuclear system is decreased, homogeneous states undergo the so-called Mott transition towards clusterised states, e.g. alpha clustering, both in nuclei and in nuclear matter. Here we investigate such a quantum phase transition (QPT) by using microscopic energy density functional (EDF) calculations both with the relativistic and the Gogny approaches on the diluted $^{16}$O nucleus. The evolution of the corresponding single-particle spectrum under dilution is studied, and a Mott-like transition is predicted at about 1/3 of the saturation density. Complementary approaches are used in order to understand this QPT. A study of spatial localisation properties as a function of the density allows to derive a value of the Mott density in agreement with the one obtained by fully microscopic calculations in $^{16}$O and in nuclear matter. Moreover a study of the spontaneous symmetry breaking of the rotational group in $^{16}$O, down to the discrete tetrahedral one, provides further insight on the features displayed by the single-particle spectrum obtained within the EDF approach.The content of the tetrahedrally deformed A-nucleon product state in terms of spherical particle-hole configurations is investigated. Finally a study of quartet condensation and the corresponding macroscopic QPT is undertaken in infinite matter.
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