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Sideband cooling is a popular method for cooling atoms to the ground state of an optical trap. Applying the same method to molecules requires a number of challenges to be overcome. Strong tensor Stark shifts in molecules cause the optical trapping potential, and corresponding trap frequency, to depend strongly on rotational, hyperfine and Zeeman state. Consequently, transition frequencies depend on the motional quantum number and there are additional heating mechanisms, either of which can be fatal for an effective sideband cooling scheme. We develop the theory of sideband cooling in state-dependent potentials, and derive an expression for the heating due to photon scattering. We calculate the ac Stark shifts of molecular states in the presence of a magnetic field, and for any polarization. We show that the complexity of sideband cooling can be greatly reduced by applying a large magnetic field to eliminate electron- and nuclear-spin degrees of freedom from the problem. We consider how large the magnetic field needs to be, show that heating can be managed sufficiently well, and present a simple recipe for cooling to the ground state of motion.
We demonstrate rotational and vibrational cooling of cesium dimers by optical pumping techniques. We use two laser sources exciting all the populated rovibrational states, except a target state that thus behaves like a dark state where molecules pile
We report enhanced three-dimensional degenerated Raman sideband cooling (3D DRSC) of caesium (Cs) atoms in a standard single-cell vapour-loading magneto-optical trap. Our improved scheme involves using a separate repumping laser and optimized lattice
A method of sideband Raman cooling to the vibrational ground state of the $m=0$ Zeeman sublevel in a far-detuned two-dimensional optical lattice is proposed. In our scheme, the Raman coupling between vibrational manifolds of the adjacent Zeeman suble
We utilize the dark state in a {Lambda}-type three-level system to cool an ensemble of 85Rb atoms in an optical lattice [Morigi et al., Phys. Rev. Lett. 85, 4458 (2000)]. The common suppression of the carrier transition of atoms with different vibrat
We show how state-dependent optical potentials can be used to trap a pair of molecules in different internal states at a separation much smaller than the wavelength of the trapping light. This close spacing greatly enhances the dipole-dipole interact