A typical f-electron Kondo lattice system Ce exhibits the well-known isostructural transition, the so-called gamma-alpha transition, accompanied by an enormous volume collapse. Most interestingly, we have discovered that a topological-phase transition also takes place in elemental Ce, concurrently with the gamma-alpha transition. Based on the dynamical mean-field theory approach combined with density functional theory, we have unravelled that the non-trivial topology in alpha-Ce is driven by the f-d band inversion, which arises from the formation of coherent 4f band around the Fermi level. We captured the formation of the 4f quasi-particle band that is responsible for the Lifshitz transition and the non-trivial Z2 topology establishment across the phase boundary. This discovery provides a concept of topology switch for topological Kondo systems. The on and off switching knob in Ce is versatile in a sense that it is controlled by available pressure (around 1 GPa) at room temperature.
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