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Spectrally-resolved observations of three pure rotational lines of H$_2$, conducted with the EXES instrument on SOFIA toward the classic bow shock HH7, reveal systematic velocity shifts between the S(5) line of ortho-H$_2$ and the two para-H$_2$ lines [S(4) and S(6)] lying immediately above and below it on the rotational ladder. These shifts, reported here for the first time, imply that we are witnessing the conversion of para-H$_2$ to ortho-H$_2$ within a shock wave driven by an outflow from a young stellar object. The observations are in good agreement with the predictions of models for non-dissociative, C-type molecular shocks. They provide a clear demonstration of the chemical changes wrought by interstellar shock waves, in this case the conversion of para-H$_2$ to ortho-H$_2$ in reactive collisions with atomic hydrogen, and provide among the most compelling evidence yet obtained for C-type shocks in which the flow velocity changes continuously.
We present high spectral resolution (~3 km/s) observations of the nu_2 ro-vibrational band of H2O in the 6.086--6.135 micron range toward the massive protostar AFGL 2591 using the Echelon-Cross-Echelle Spectrograph (EXES) on the Stratospheric Observa
We investigate the evolution of the ortho-to-para ratio of overall (gas + ice) H$_2$ via the nuclear spin conversion on grain surfaces coated with water ice under physical conditions that are relevant to star- and planet-forming regions. We utilize t
The H2 molecule has two nuclear spin isomers, the so-called ortho and para isomers. Nuclear spin conversion (NSC) between these states is forbidden in the gas phase. The energy difference between the lowest ortho and para states is as large as 14.7 m
We have used the Herschel-HIFI instrument to observe both nuclear spin symmetries of amidogen (NH2) towards the high-mass star-forming regions W31C (G10.6-0.4), W49N (G43.2-0.1), W51 (G49.5-0.4) and G34.3+0.1. The aim is to investigate the ratio of n
(Abridged) We present a large sample of o-H$_2$D$^+$ observations in high-mass star-forming regions and discuss possible empirical correlations with relevant physical quantities to assess its role as a chronometer of star-forming regions through diff