We apply the bi-moment determinant method to compute a representation of the matrix product algebra -- a quadratic algebra satisfied by the operators $mathbf{d}$ and $mathbf{e}$ -- for the five parameter ($alpha$, $beta$, $gamma$, $delta$ and $q$) Asymmetric Simple Exclusion Process. This method requires an $LDU$ decomposition of the ``bi-moment matrix. The decomposition defines a new pair of basis vectors sets, the `boundary basis. This basis is defined by the action of polynomials ${P_n}$ and ${Q_n}$ on the quantum oscillator basis (and its dual). Theses polynomials are orthogonal to themselves (ie. each satisfy a three term recurrence relation) and are orthogonal to each other (with respect to the same linear functional defining the stationary state). Hence termed `bi-orthogonal. With respect to the boundary basis the bi-moment matrix is diagonal and the representation of the operator $mathbf{d}+mathbf{e}$ is tri-diagonal. This tri-diagonal matrix defines another set of orthogonal polynomials very closely related to the the Askey-Wilson polynomials (they have the same moments).
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